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How Does Silicon Carbide Ceramic Compare to Alumina Ceramics?

Introduction

Silicon carbide and alumina are two of the most widely used advanced ceramics. Their performance diverges in specific areas. You may their weigh the pros and cons when choosing one of them. This article highlights the difference between them, helping you to choose the most suitable one for your industrial application.

Silicon Carbide Balls and Alumina Balls
Silicon Carbide Balls and Alumina Balls

What is Silicon Carbide?

Silicon carbide (SiC) is an advanced ceramic made of silicon and carbon. It exists in several forms, such as SSiC and RBSiC. This material has several applications across different industries because of its:

  • Excellent hardness
  • Outstanding wear &corrosion resistance
  • Good thermal conductivity of 120-150 W/mK
  • Low thermal expansion of 5×10-6/℃

These properties make SiC maintain its strength even at high temperatures of 1600℃. It is widely used in the semiconductor, chemical and other industries.

Silicon Carbide Ceramic Components for Semiconductors Manufacturing
Silicon Carbide Ceramic Components for Semiconductors Manufacturing

What is Alumina?

Alumina, also known as aluminum oxide, is one of the classic engineering ceramic. It is known for:

  • Good hardness
  • Excellent electrical insulation
  • Stable performance up to ~1300℃
  • Low cost and easier machining

Alumina possesses lower toughness and thermal shock resistance than SiC. It is less suitable for thermal cycling under severe environmental conditions.

A Comparison of Silicon Carbide vs. Alumina

Mechanical Strength

With a flexural strength up to 700 MPa and high hardness over 2200 HV, SiC has 2 times higher durability than alumina. Its toughness prevents crack, extending the service life of components such as nozzles, seals and bearings.

Thermal Stability

SiC’s thermal conductivity of 120-150 W/m·K is nearly six times than that of alumina. It ensures efficient heat dissipation in electronics and semiconductor systems. Its low expansion coefficient of 4.5×10-6/℃ gives excellent resistance to thermal shock during rapid temperature changes.

Chemical Resistance

SiC resists acids and alkalis even under harsh conditions. Its corrosion rate in 90℃ nitric acid is less than 0.01 mm per year. In contrast, that of alumina is 0.12 mm per year. It shows SiC is ideal for corrosive chemical processing systems.

Weight

SiC has a density of about 3.2 g/cm3, around 30% lighter than alumina. Thus, using SiC can reduce loads and improve efficiency, which is important for aerospace and high-speed machinery applications.

Cost

Raw materials of SiC are 3-5× more expensive and harder to machine. Long-term performance, however, reduces the overall operating costs due to lower replacement frequency and higher reliability.

A summarized comparison of the two materials is given in the following chart.

Properties Comparison of SiC and Alumina

PropertySilicon Carbide (SiC)Alumina (Al2O3)
Density (g/cm3)3.15-3.223.7-3.9
Hardness (HV)2200-30001500-1800
Flexural Strength (MPa)500-700350-400
Fracture Toughness (MPa·m1/2)5-73-4.5
Thermal Conductivity (W/m·K)120-15020-32
Thermal Expansion (10-6/℃)4.57.5-8.2
Max Service Temp (℃)1600 (inert atmosphere)1300 (air)
Electrical Resistivity (Ω·cm, 20℃)>106 (semiconductive)>1014 (insulator)
Corrosion Rate (90℃ HNO3)<0.01 mm/year<0.12 mm/year
MachinabilityHard, requires diamond toolsEasier, conventional tools
Material Cost3-5× of aluminaLower

In conclusion, SiC provide superior strength, wear and thermal performance. Alumina offers lower cost and easier processing for general applications.

Application Examples

SiC has an excellent property in high-performance and harsh-environment applications. Alumina is still popular in cost-efficient and insulating designs.

SiC

The advantages of the silicon carbide ceramic lie in its resistance to high temperatures, high thermal conductivity and resistance to high-wear environments.

Metal Melting Crucibles: The excellent thermal conductivity of SiC ranges from 90 to 150 W/m·K, which makes it an ideal material in the manufacture of metal melting crucibles, such as for aluminum, copper and zinc. This leads to improved melting efficiency and reduced energy consumption.

NKM Silicon Carbide Crucibles and Their Applications
NKM Silicon Carbide Crucibles and Their Applications

Semiconductor Manufacturing Equipment: SiC has high thermal conductivity, low thermal expansion and corrosion resistance. It finds application in polishing pads, precision motion platforms and focusing rings inside equipment like photolithography machines and etching tools, which resulting in better process purity and equipment stability.

Ballistic Armor: SiC, with its hardness and low density, is applied in ballistic plates, which offer 20% lighter weight compared with alumina for similar protection. This makes it more cost-effective than boron carbide and hence finds wide application in personal protection equipment and specialized vehicle armor.

Chemical and Wear Parts: SiC has excellent resistance to strong acids and alkalis, along with extreme wear resistance higher than metals by over a factor of 10. Thus, SiC is suitable for numerous extreme duties in harsh chemical environments, such as nozzles, valve seats, and pipe liners.

Al2O3

On the other hand, alumina is especially superior for its high electrical insulation. In addition, alumina is cheaper and has broader applications.

Insulating Semiconductor Parts: The excellent electrical insulation of alumina, along with its low cost, has made it very effective for semiconductor equipment like wafer polishing plates, vacuum suction cups, and boats. It is suitable for applications where thermal conductivity is not a critical factor.

Manufacturing Process of NKM Alumina Semiconductor Ceramics
Manufacturing Process of NKM Alumina Semiconductor Ceramics

Mechanical Seals and Bearings: Alumina-based seals and bearings find wide applications in oil and chemical industries due to their resistance against corrosion and wear, hence constituting a more cost-effective solution for applications in medium-loaded conditions than SiC.

Electronic Substrates and Packaging: Due to its superior insulation performance and mature manufacturing processes, alumina has been widely used in packaging substrates and circuit boards of LEDs, though it exhibits lower thermal conductivity compared to alumina nitride or SiC.

Industrial Parts: In applications such as valve seats, cutting tools, and wear liners, alumina provides a very cost-effective solution where temperature demands are moderate, usually below 1200℃, and extreme thermal conductivity is not needed.

In extreme environments, silicon carbide offers superior performance in high-temperature, high-conductivity and high-wear applications. It’s well-suited for advanced industrial applications. On the other hand, alumina has more advantageous uses in applications that require high electrical insulation, moderate temperatures and cost efficiency.

SiC or Alumina?

Selecting which ceramic mainly depends on your working environment. Temperature, mechanical stress, chemical exposure and budget. We summarizes some typical use-case recommendations, helping quickly determine when SiC provides long-term benefits.

For applications above 1200℃, where there is thermal shock and extreme heat, SiC is preferred. It does not lose its strength and will not crack under harsh conditions. This makes it ideal for semiconductor manufacturing and in spacecraft.

In harsh conditions of wear or corrosion, SiC shows excellent resistance to wear and aggressive chemical media. This makes SiC very suitable for nozzles, seals or other components in those industrial applications where abrasive materials or chemicals are used.

NKM Silicon Carbide Sealing Ring
NKM Silicon Carbide Sealing Ring

For applications requiring efficient heat dissipation, like semiconductors and substrates, SiC provides superior thermal conductivity that allows better performance in electronics requiring rapid heat transfer.

Alumina is more suited to applications needed electrical insulation at moderate temperatures. It has excellent dielectric properties and functions well in those electrical components operating at lower temperatures that call for reliable insulation.

In cost-sensitive large manufacture, alumina shows better value because of its lower cost. It is also easy to machine. Alumina is suitable for general applications that do not require the extreme properties of SiC.

SiC vs Alumina: Which Advanced Ceramic is Right for Your Industry?

SiC and alumina are play key roles in modern industry. SiC clearly leads in mechanical strength, thermal performance and corrosion resistance. Thought its production and machining costs are higher, SiC provides better durability for harsh industries from semiconductors to aerospace. For applications that need high temperature, wear or corrosion resistance, SiC delivers long-term value.

Today, there is an increasing reliance on advanced ceramics like SiC. Many industries use it to enhance efficiency and durability. Working with a reliable and experienced ceramic manufacturer becomes more and more important. From material selection to delivery, a dependable partner can ensure consistent quality for long-term performance.

Silicon Carbide Ceramic Components Manufactured by NKM
Silicon Carbide Ceramic Components Manufactured by NKM

Newthink New Materials has been dedicated to providing advanced ceramic components for over 14 years. NKM serves across more than 40 countries. If you are interested in SiC ceramic products or want to explore how they support your projects, please check our page for more details.

Reference

[1] Izhevskyi, V. A., Genova, L. A., Bressiani, J. C., & Bressiani, A. H. A. (2000). silicon carbide. Structure, properties and processing. Cerâmica46, 4-13.

[2] Ben-Nissan, B., Choi, A. H., & Cordingley, R. (2008). Alumina ceramics. In Bioceramics and their clinical applications (pp. 223-242). Woodhead Publishing.

[3] Abderrazak, H., & Hmida, E. S. B. H. (2011). Silicon carbide: synthesis and properties. Properties and applications of Silicon Carbide, 361-388.

[4] Lim, K. Y., Kim, Y. W., & Kim, K. J. (2014). Mechanical properties of electrically conductive silicon carbide ceramics. Ceramics International40(7), 10577-10582.

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